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HofF height of fundus
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GEE generalized estimating equation
SBM Solomon-Bloembergen-Morgan [equation]
VSIE volume surface integral equation [method]
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ODE ordinary differential equation
SEM Structural Equation Modeling
VHL Van Hippel-Lindau disease
VWS Van der Woude syndrome
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van't Hoff's equation Equation for osmotic pressure of dilute solutions.
See: van't Hoff's law.
For any reaction, d(ln Keq/d(1/T) equals -dH/R where Keq is the equilibrium constant, T the absolute temperature, R is the universal gas constant, and dH is the change in enthalpy; thus, plotting ln Keq vs. 1/T allows the determination of dH.
(05 Mar 2000)
van't Hoff, Jacobus <person> Dutch chemist and Nobel laureate, 1852-1911.
See: van't Hoff's equation, van't Hoff's law, van't Hoff's theory, Le Bel-van't Hoff rule.
(05 Mar 2000)
van't Hoff's law In stereochemistry, all optically active substances have one or more multivalent atoms united to four different atoms or radicals so as to form in space an unsymmetrical arrangement, the osmotic pressure exerted by any substance in very dilute solution is the same that it would exert if present as gas in the same volume as that of the solution; or, at constant temperature, the osmotic pressure of dilute solutions is proportional to the concentration (number of molecules) of the dissolved substance; i.e., the osmotic pressure, &pi;, in dilute solutions is &pi; = RT&sigma;ci, where R is the universal gas constant, T is the absolute temperature, and ci is the molar concentration of solute i, the rate of chemical reactions increases between two-and three-fold for each 10°C rise in temperature.
(05 Mar 2000)
van't Hoff's theory That substances in dilute solution obey the gas laws.
Compare: van't Hoff's law.
(05 Mar 2000)
Le Bel-van't Hoff rule The number of stereoisomers of an organic compound is 2n where n represents the number of asymmetric carbon atoms (unless there is an internal plane of symmetry). A corollary of their simultaneously announced conclusions, in 1874, that the most probable orientation of the bonds of a carbon atom linked to four groups or atoms is toward the apexes of a tetrahedron, and that this accounted for all then-known phenomena of molecular asymmetry (which involved a carbon atom bearing four different atoms or groups).
See: stereoisomerism.
(05 Mar 2000)
alveolar gas equation The equation defining the steady state relation of the alveolar oxygen pressure to the barometric pressure, inspired gas composition, alveolar carbon dioxide pressure, and respiratory exchange ratio; the equation is used in various forms depending upon which simplifying assumptions are acceptable for different applications.
(05 Mar 2000)
arrhenius equation This equation expresses the logarithmic relationship between the rate constant of a reaction and the reciprocal of the temperature (expressed in K).
(09 Oct 1997)
Bohr's equation An equation to calculate the respiratory dead space from the fact that gas expired from the lungs is a mixture of gas from the dead space and gas from the alveoli, i.e., the dead space volume divided by the tidal volume equals the difference between alveolar and mixed expired gas composition, divided by the difference between alveolar and inspired gas composition; gas composition can be expressed in any consistent units of concentration or partial pressure of oxygen or carbon dioxide.
(05 Mar 2000)
boltzmann equation <radiobiology> Fundamental equation in kinetic theory which describes the evolution of the distribution function. (See also Vlasov equation.) The actual equation is given in most texts covering plasma kinetic theory.
(09 Oct 1997)
Gay-Lussac's equation The overall chemical equation for alcoholic fermentation; C6H12O6 = 2CO2 + 2CH3CH2OH.
(05 Mar 2000)
rate equation A mathematical expression for a chemical, radiochemical, or enzyme-catalyzed reaction.
(05 Mar 2000)
Rayleigh equation A ratio of red to green required by each observer to match spectral yellow.
Synonym: Rayleigh test.
(05 Mar 2000)
Gibbs-Helmholtz equation An equation expressing the relationship in a galvanic cell between the chemical energy transformed and the maximal electromotive force obtainable.
(05 Mar 2000)
Victor-Michaelis-Menten equation <chemistry> Equation derived from a simple kinetic model for a single-substrate non-cooperative enzyme-catalyzed reaction that successfully accounts for the hyperbolic adsorption isotherm) relationship between substrate concentration and reaction rate.
V = Vmax x S/(S + Km), where V is the initial velocity of the reaction, Km is the Michaelis constant, Vmax is the maximum rate approached by very high substrate concentrations and S is the initial substrate concentration.
Similar equations can be derived for conditions in which the product is present and for multisubstrate enzymes.
Synonym: Victor-Michaelis-Menten equation.
(12 Jul 2000)
Goldman equation An equation derived to predict membrane potentials in terms of the membrane's permeability to ions and their concentrations on either side.
Synonym: constant field equation, Goldman-Hodgkin-Katz equation, GHK equation.
(05 Mar 2000)
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