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phosphoglycerides Acylglycerol and diacylglycerol phosphates;constituents of nerve tissue, and involved in fat transport and storage.
(05 Mar 2000)
phosphoglyceromutase An isomerizing enzyme catalyzing the reversible interconversion of 2-phosphoglycerate and 3-phosphoglycerate with 2,3-bisphosphoglycerate present as a cofactor; a deficiency of this enzyme, which plays a role in glycolysis, is an inherited disorder that results in an intolerance for strenuous exercise.
(05 Mar 2000)
phosphoheptose isomerase <enzyme> Sedoheptulose-7-p is converted to d-glycero-d-manno-heptulose
Registry number: EC 5.3.1.-
(26 Jun 1999)
phosphohexokinase <enzyme> An enzyme that catalyses the conversion of a nucleotide triphosphate and a sugar phosphate to a nucleotide diphosphate and a sugar diphosphate. D-fructose 6-phosphate, d-tagatose 6-phosphate, and sedoheptulose 7-phosphate can act as acceptors; ATP, utp, ctp, and itp can act as donors. A deficiency of this enzyme is the cause of glycogen storage disease type vii.
Chemical name: ATP:D-fructose-6-phosphate 6-phosphotransferase
Registry number: EC 2.7.1.11
(12 Dec 1998)
phosphohexomutase <enzyme> An enzyme that catalyses the reversible interconversion of d-fructose 6-phosphate and d-glucose-6-phosphate; a part of glycolysis and gluconeogenesis; glucosephosphate isomerase deficiency is an inherited disorder resulting in liver glycogenesis and haemolytic anaemia.
Synonym: hexosephosphate isomerase, phosphohexomutase, phosphohexose isomerase.
(05 Mar 2000)
phosphohexose isomerase <enzyme> An enzyme that catalyses the reversible interconversion of d-fructose 6-phosphate and d-glucose-6-phosphate; a part of glycolysis and gluconeogenesis; glucosephosphate isomerase deficiency is an inherited disorder resulting in liver glycogenesis and haemolytic anaemia.
Synonym: hexosephosphate isomerase, phosphohexomutase, phosphohexose isomerase.
(05 Mar 2000)
phosphohexose isomerase deficiency <enzyme> An enzyme deficiency characterised by chronic nonspherocytic haemolytic anaemia; autosomal recessive inheritance.
Synonym: phosphohexose isomerase deficiency.
(05 Mar 2000)
phosphohydrolases Phosphoric monoester hydrolases;enzymes (EC sub-subclass 3.1.3) cleaving phosphoric acid (as orthophosphate) from its esters; trivial names usually end in phosphate.
(05 Mar 2000)
phosphoinositide <biochemistry> A phosphatidic acid combined with inositol found in biomembranes and a precursor to certain cellular signals. Sometimes referred to as inositide.
It is a very important minor phospholipid in eukaryotes, involved in signal transduction processes. Contains myo inositol linked through the 1 hydroxyl group to phosphatidic acid.
The 4 phosphate (PIP) and 4, 5 bisphosphate derivatives PIP2) are formed and broken down in membranes by the action of specific kinases and phosphatases (futile cycles).
Signal sensitive phospholipase C enzymes remove the inositol moiety, in particular from 1,4,5 trisphosphate (PIP2) as inositol 1,4,5 triphosphate (Ins P3: IP3). Both the diacyl glycerol and products act as second messengers.
Synonym: phosphoinositide.
(20 Sep 2002)
phosphokinase A phosphotransferase or a kinase.
(05 Mar 2000)
phospholamban kinase <enzyme> A delta-cam kinase isozyme; catalyses the phosphorylation of phospholamban
Registry number: EC 2.7.1.-
Synonym: phospholamban sarcoplasmic reticulum calmodulin-dependent protein kinase, phospholamban srcam kinase
(26 Jun 1999)
phospholamban phosphatase <enzyme> Purified from canine cardiac cytosol; dephosphorylates pholamban; stimulated by mg+2, mn+2 or ca+2
Registry number: EC 3.1.3.-
(26 Jun 1999)
phospholipase <enzyme> That hydrolyse ester bonds in phospholipids. They comprise two types: aliphatic esterases (phospholipase A1, A2 and B) that release fatty acids and phosphodiesterases (types C and D) that release diacyl glycerol or phosphatidic acid respectively.
Type A2 is widely distributed in venoms and digestive secretions. Types A1, A2 and C the latter specific for phosphatidyl inositol) are present in all mammalian tissues. Type C is also found as a highly toxic secretion product of pathogenic bacteria. Type B attacks monoacyl phospholipids and is poorly characterised. Type D is largely of plant origin. PLA2 Type II (a secreted enzyme, but not the same as the Type I digestive pancreatic enzyme) is probably very important in inflammation because its action can release arachidonic acid, the starting point for eicosanoid synthesis.
Phosphatidyl inositol bisphosphate specific phospholipase C is important in generating diacyl glycerol and inositol trisphosphate, both second messengers.
(31 Dec 1997)
phospholipase A1 <enzyme> An enzyme that hydrolyzes a lecithin (1,2-diacylglycerophosphocholine) to a 2-acylglycerophosphocholine and a fatty acid anion.
(05 Mar 2000)
phospholipase A2 <enzyme> An enzyme that catalyses the hydrolysis of a lecithin to a lysolecithin by removing the 2-acyl group; also acts on other phospholipids by removing a fatty acid from the 2-position; this enzyme has an important role in prostaglandin and leukotriene biosynthesis.
Synonym: lecithinase A, phosphatidase, phosphatidolipase.
(05 Mar 2000)
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