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thiamin pyridinylase <enzyme> An enzyme catalyzing transfer of a pyridine or other bases into the position of the pyrimidine in thiamin; e.g., thiamin reacting with pyridine produces heteropyrithiamin and 4-methyl-5-(2'-hydroxyethyl)-thiazole.
Synonym: pyrimidine transferase, thiaminase I.
(05 Mar 2000)
thiamin pyrophosphate The diphosphoric ester of thiamin, a coenzyme of several (de)carboxylases, transketolases, and alpha-oxoacid dehydrogenases.
Synonym: aneurine pyrophosphate, cocarboxylase, diphosphothiamin.
(05 Mar 2000)
thiamin pyrophosphokinase <enzyme> An enzyme that catalyses the formation of thiamine pyrophosphate from ATP and thiamine.
Chemical name: ATP:thiamine pyrophosphotransferase
Registry number: EC 2.7.6.2
(12 Dec 1998)
thiamin-triphosphatase <enzyme> An enzyme present in nerve tissue. It catalyses reversibly the formation of thiamine diphosphate and orthophosphate from thiamine triphosphate.
Chemical name: Thiamin-triphosphate phosphohydrolase
Registry number: EC 3.6.1.28
(12 Dec 1998)
thiaminase 1. An enzyme present in raw fish that destroys thiamin and may produce thiamin deficiency in animals on a diet largely composed of raw fish.
2. A hydrolase cleaving thiamin into a pyrimidine moiety (i.e., 2-methyl-4-amino-5-hydroxymethylpyrimidine) and a thiazole moiety (i.e., 4-methyl-5-(2'-hydroxyethyl)-thiazole); the pyrimidine moiety may appear in the urine as pyramin.
Synonym: thiaminase II.
(05 Mar 2000)
thiaminase I <enzyme> An enzyme catalyzing transfer of a pyridine or other bases into the position of the pyrimidine in thiamin; e.g., thiamin reacting with pyridine produces heteropyrithiamin and 4-methyl-5-(2'-hydroxyethyl)-thiazole.
Synonym: pyrimidine transferase, thiaminase I.
(05 Mar 2000)
thiaminase II 1. An enzyme present in raw fish that destroys thiamin and may produce thiamin deficiency in animals on a diet largely composed of raw fish.
2. A hydrolase cleaving thiamin into a pyrimidine moiety (i.e., 2-methyl-4-amino-5-hydroxymethylpyrimidine) and a thiazole moiety (i.e., 4-methyl-5-(2'-hydroxyethyl)-thiazole); the pyrimidine moiety may appear in the urine as pyramin.
Synonym: thiaminase II.
(05 Mar 2000)
thiamine <chemical> 3-((4-amino-2-methyl-5-pyrimidinyl)methyl)-5-(2- hydroxyethyl)-4-methylthiazolium chloride.
Chemical name: Thiazolium, 3-((4-amino-2-methyl-5-pyrimidinyl)methyl)-5-(2-hydroxyethyl)-4-methyl- chloride
(12 Dec 1998)
thiamine deficiency A nutritional condition produced by a deficiency of thiamine in the diet, characterised by anorexia, irritability, and weight loss. Later, patients experience weakness, peripheral neuropathy, headache, and tachycardia. In addition to being caused by a poor diet, thiamine deficiency in the united states most commonly occurs as a result of alcoholism, since ethanol interferes with thiamine absorption. In countries relying on polished rice as a dietary staple, beriberi prevalence is very high.
(12 Dec 1998)
thiamine monophosphate <chemical> Thiamine dihydrogen phosphate ester. The monophosphate ester of thiamine.
Synonym: monophosphothiamine; vitamin b1 monophosphate.
Chemical name: Thiazolium, 3-((4-amino-2-methyl-5-pyrimidinyl)methyl)-4-methyl-5-(2-(phosphonooxy)ethyl)-, chloride
(12 Dec 1998)
thiamine pyrophosphatase <enzyme> The coenzyme form of vitamin B1 (thiamine), deficiency of which causes beri beri. Forms the prosthetic group of pyruvate dehydrogenase, _ ketoglutarate dehydrogenase and transketolase, in which it is involved in transfer of a 2 carbon unit. Marker for the trans cisternae of the Golgi complex.
(18 Nov 1997)
thiamine pyrophosphate <biochemistry> Co carboxylase. A cofactor that has an unusually acidic carbon atom able to form carbon carbon bonds. Found in pyruvate dehydrogenase and transketolase.
(18 Nov 1997)
thiamine triphosphate <chemical> 3-((4-amino-2-methyl-5-pyrimidinyl)methyl)-4-methyl-5-(4,6,8,8-tetrahydroxy-3,5,7-trioxa-4,6,8-triphosphaoct-1-yl)thiazolium hydroxide, inner salt, p,p',p''-trioxide. The triphosphate ester of thiamine. In leigh's disease, this compound is present in decreased amounts in the brain due to a metabolic block in its formation.
Chemical name: Thiazolium, 3-((4-amino-2-methyl-5-pyrimidinyl)methyl)-4-methyl-5-(4,6,8,8-tetrahydroxy-3,5,7-trioxa-4,6,8-triphosphaoct-1-yl)-, inner salt, P,P',P''-trioxide
(12 Dec 1998)
thiamphenicol <chemical> 2,2-dichloro-n-(2-hydroxy-1-(hydroxymethyl)-2-(4- (methylsulfonyl)phenyl)ethyl)acetamide. A methylsulfonyl analog of chloramphenicol. It is an antibiotic and immunosuppressive agent.
Pharmacological action: antibiotics, immunosuppressive agents.
Chemical name: Acetamide, 2,2-dichloro-N-(2-hydroxy-1-(hydroxymethyl)-2-(4-(methylsulfonyl)phenyl)ethyl)-, (R-(R*,R*))-
(12 Dec 1998)
thiamylal <chemical> A barbiturate that is administered intravenously for the production of complete anaesthesia of short duration, for the induction of general anaesthesia, or for inducing a hypnotic state.
Pharmacological action: anaesthetics, intravenous, sedatives, barbiturate.
Chemical name: 4,6(1H,5H)-Pyrimidinedione, dihydro-5-(1-methylbutyl)-5-(2-propenyl)-2-thioxo-
(12 Dec 1998)
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