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carbamate kinase A phosphotransferase catalyzing the reaction of carbamoyl phosphate and ADP to form ATP, NH3, and CO2.
(05 Mar 2000)
carbamates Salts or esters of carbamic acid. They contain the general formula nh2-coo-.
(12 Dec 1998)
carbamazepine <drug> This tricyclic prescription drug is used to treat convulsions, epilepsy and manic episodes.
(09 Oct 1997)
carbamic acid A hypothetical acid, NH2-COOH, forming carbamates; the acyl radical is carbamoyl.
(05 Mar 2000)
carbamide An obsolete term for urea.
(05 Mar 2000)
carbamino compound Any carbamic acid derivative formed by the combination of carbon dioxide with a free amino group to form an N-carboxy group, -NH-COOH, as in haemoglobin forming carbaminohemoglobin.
(05 Mar 2000)
carbaminohemoglobin Carbon dioxide bound to haemoglobin by means of a reactive amino group on the latter, i.e., Hb-NHCOOH; approximately 20% of the total content of carbon dioxide in blood is combined with haemoglobin in this manner.
Synonym: carbhemoglobin, carbohemoglobin.
(05 Mar 2000)
carbamoate 1. A salt or ester of carbamic acid forming the basis of urethane hypnotics.
2. A group of cholinesterase inhibiting insecticides resembling organophosphates; the most frequent carbamate is carbaril.
Synonym: carbamoate, carbaril.
(05 Mar 2000)
carbamoyl The acyl radical, NH2-CO-, the transfer of which plays an important role in certain biochemical reactions; e.g., in the urea cycle, via carbamoyl phosphate.
(05 Mar 2000)
carbamoyl phosphate H2NCO-OPO32-;a reactive intermediate capable of transferring its carbamoyl group (H2NCO-) to an acceptor molecule, forming citrulline from ornithine in the urea cycle, and ureidosuccinic acid from aspartic acid in pyrimidine ring formation.
(05 Mar 2000)
carbamoyl phosphate synthetase A phosphotransferase catalyzing the formation of carbamoyl phosphate. There are two significant isozymes. Carbomoyl phosphate synthetase I is a mitochondrial enzyme that catalyses the reaction of 2ATP, NH3, CO2, and H2O to carbamoyl phosphate, 2ADP, and Pi. It is activated by N-acetylglutamate and participates in urea biosynthesis.
A deficiency of carbamoyl phosphate synthetase I can result in hyperammonaemia. Carbamoyl phosphate synthetase II is a cytosolic enzyme that, under physiological conditions, uses l-glutamine as the nitrogen source (producing l-glutamate) instead of NH3, is not activated by N-acetylglutamate, and is found in pyrimidine biosynthesis.
(05 Mar 2000)
carbamoyl-phosphate synthase (ammonia) <enzyme> An enzyme that catalyses the formation of carbamoyl phosphate from ATP, carbon dioxide, and ammonia. This enzyme is specific for arginine biosynthesis or the urea cycle.
Chemical name: Carbon dioxide:ammonia ligase (ADP-forming, carbamate-phosphorylating)
Registry number: EC 6.3.4.16
(12 Dec 1998)
carbamoyl-phosphate synthase (glutamine-hydrolyzing) <enzyme> An enzyme that catalyses the formation of carbamoyl phosphate from ATP, carbon dioxide, and glutamine. This enzyme is important in the de novo biosynthesis of pyrimidines.
Chemical name: Carbon dioxide:L-glutamine amido-ligase (ADP-forming, carbamate-phosphorylating)
Registry number: EC 6.3.5.5
(12 Dec 1998)
carbamoylaspartate dehydrase dihydro-orotase
carbamoylation Transfer of the carbamoyl from a carbamoyl-containing molecule (e.g., carbamoyl phosphate) to an acceptor moiety such as an amino group.
(05 Mar 2000)
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