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oxidation-reduction A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs.
(12 Dec 1998)
oxidation-reduction electrode An electrode capable of measuring oxidation-reduction potential.
See: quinhydrone electrode.
Synonym: redox electrode.
(05 Mar 2000)
oxidation-reduction indicator A substance that undergoes a definite colour change at a specific oxidation potential.
Synonym: redox indicator.
(05 Mar 2000)
oxidation-reduction potential <chemistry, physics> The potential in volts of an inert metallic electrode measured in a system of an arbitrarily chosen ratio of [oxidant] to [reductant] and referred to the normal hydrogen electrode at absolute temperature.
It is calculated from the following equation: where R is the gas constant expressed in electrical units, T the absolute temperature (Kelvin), n the number of electrons transferred, F the faraday and E0 the normal symbol for the potential of the system at pH 0; for biological systems E0' is often used (in which pH = 7).
Compare: Nernst's equation.
Synonym: redox potential.
(05 Mar 2000)
oxidation-reduction reaction <chemistry> Any reaction in which electrons are removed from one molecule or atom and given to another molecule or atom.
(09 Oct 1997)
oxidation-reduction system <enzyme> An enzyme system in the tissues by which oxidation and reduction proceed simultaneously through the transference of hydrogen or of one or more electrons from one metabolite to another.
See: oxidation-reduction.
Synonym: redox system.
(05 Mar 2000)
colourimetric titration A titration in which the end point is marked by a colour change.
(05 Mar 2000)
whole-body titration curve A graphic representation of the in vivo changes in hydrogen ion, PaCO2, and bicarbonate which occur in arterial blood in response to primary acid-base disturbances.
(05 Mar 2000)
potentiometric titration A titration during which the pH is continually measured with some value of the pH serving as end point.
(05 Mar 2000)
skin test end-point titration A quantitative form of intradermal testing for the relative allergenicity of a substance. It is used to determine the amount of an allergen that will be tolerated in immunotherapy.
(12 Dec 1998)
titration <chemistry> The act or process of titrating; a substance obtained by titrating.
Source: Websters Dictionary
(01 Mar 1998)
formol titration A method of titrating the amino groups of amino acids, by adding formaldehyde to the neutral solution; the formaldehyde reacts with the NH3+ group, liberating an equivalent quantity of H+, which may then be estimated by titration with NaOH.
(05 Mar 2000)
algal oxidation pond <ecology> A wide, shallow pond used in waste water treatment, the algae produce oxygen so that bacteria can aerobically digest sewage in the water.
(09 Oct 1997)
alpha-oxidation A form of oxidation of fatty acids in which carbons are removed one at a time in the form of CO2; the alpha-carbon is first hydroxylated and then converted into a carbonyl; a deficiency of this pathway is associated with Refsum's disease.
(05 Mar 2000)
auto-oxidation The direct combination of a substance with molecular oxygen at ordinary temperatures.
Synonym: autoxidation.
(05 Mar 2000)
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