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oxidation-reduction potential <chemistry, physics> The potential in volts of an inert metallic electrode measured in a system of an arbitrarily chosen ratio of [oxidant] to [reductant] and referred to the normal hydrogen electrode at absolute temperature.
It is calculated from the following equation: where R is the gas constant expressed in electrical units, T the absolute temperature (Kelvin), n the number of electrons transferred, F the faraday and E0 the normal symbol for the potential of the system at pH 0; for biological systems E0' is often used (in which pH = 7).
Compare: Nernst's equation.
Synonym: redox potential.
(05 Mar 2000)
oxidation-reduction A chemical reaction in which an electron is transferred from one molecule to another. The electron-donating molecule is the reducing agent or reductant; the electron-accepting molecule is the oxidizing agent or oxidant. Reducing and oxidizing agents function as conjugate reductant-oxidant pairs or redox pairs.
(12 Dec 1998)
oxidation-reduction electrode An electrode capable of measuring oxidation-reduction potential.
See: quinhydrone electrode.
Synonym: redox electrode.
(05 Mar 2000)
oxidation-reduction indicator A substance that undergoes a definite colour change at a specific oxidation potential.
Synonym: redox indicator.
(05 Mar 2000)
oxidation-reduction reaction <chemistry> Any reaction in which electrons are removed from one molecule or atom and given to another molecule or atom.
(09 Oct 1997)
oxidation-reduction system <enzyme> An enzyme system in the tissues by which oxidation and reduction proceed simultaneously through the transference of hydrogen or of one or more electrons from one metabolite to another.
See: oxidation-reduction.
Synonym: redox system.
(05 Mar 2000)
reduction potential The inherent tendency of a compound to act as an electron donor or an electron acceptor. Measured in volts.
(09 Oct 1997)
algal oxidation pond <ecology> A wide, shallow pond used in waste water treatment, the algae produce oxygen so that bacteria can aerobically digest sewage in the water.
(09 Oct 1997)
alpha-oxidation A form of oxidation of fatty acids in which carbons are removed one at a time in the form of CO2; the alpha-carbon is first hydroxylated and then converted into a carbonyl; a deficiency of this pathway is associated with Refsum's disease.
(05 Mar 2000)
auto-oxidation The direct combination of a substance with molecular oxygen at ordinary temperatures.
Synonym: autoxidation.
(05 Mar 2000)
beta-oxidation <biochemistry> The oxidative breakdown of fatty acids into acetyl-coenzyme A by repeated oxidation at the beta-carbon atom.
Oxidation of the beta-carbon (carbon 3) of a fatty acid causes the formation of the beta-keto (beta-oxo) acid analog. This is of importance in fatty acid catabolism, the entire pathway for the catabolism of saturated fatty acids containing an even number of carbon atoms. Beta-oxidation is a part of this pathway and acetyl-CoA is a major product of this pathway.
(05 Mar 2000)
beta-oxidation-condensation theory <biochemistry> That the two carbon fragments split from the fatty acid molecule by beta-oxidation are converted to acetic acid and then condensed to acetoacetic acid.
(05 Mar 2000)
biological oxidation Decomposition of organic materials by microorganisms.
(05 Dec 1998)
Meyerhof oxidation quotient <biochemistry> An index for the effect of oxygen on glycolysis and on fermentation (i.e., on the Pasteur effect); equal to the rate of anaerobic fermentation minus the rate of aerobic respiration divided by the rate of oxygen uptake.
(21 Jun 2000)
pyruvate oxidation factor <biochemistry> 1,2 dithiolane 3 valeric acid. Regarded as a coenzyme in the oxoglutarate dehydrogenase complex of the citric acid cycle. Involved generally in oxidative decarboxylations of _ keto acids. A growth factor for some organisms.
(18 Nov 1997)
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