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chlorophyll synthetase <enzyme> Incorporates geranylgeraniol into chlorophyll; requires ATP; as of 11/80 not clear whether this is a synthetase or a combination of a kinase and a transferase
Registry number: EC 6.1.-
(26 Jun 1999)
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chlorophyll The photosynthetic pigments of higher plants, but closely related to bacteriochlorophylls. Magnesium complexes of tetrapyrolles.
(18 Nov 1997)
chlorophyll a Magnesium(II) pheophytinate a [(pheophytina to a)magnesium(II)];the major pigment found in all oxygen-evolving photosynthetic organisms (higher plants, and red and green algae).
(05 Mar 2000)
chlorophyll b (CH3 at 7 replaced by CHO in the chlorophyll structure), magnesium(II) pheophytinate b [(pheophytinato b) magnesium(II)]; the chlorophyll generally characteristic of higher plants (including the Chlorophyta, Euglenaphyta, and green algae). Absent in other types of algae.
(05 Mar 2000)
chlorophyll b reductase <enzyme> Reduces the 7-formyl group of chlorophyll b to the 7'-hydroxy compound; requires NADPH or NADH; NADPH is more effective
Registry number: EC 1.1.1.-
Synonym: chlorophyllide b reductase
(26 Jun 1999)
chlorophyll c The chlorophyll present in brown algae, diatoms, and flagellates. Two variants are known: c 1, in which two hydrogens are lost from C-17 and C-18, thus resembling phytoporphyrin, and the side chain at C-17 becomes an acrylic residue, -CH==CH2COOH; c2, in which the same changes are noted, but two more hydrogens are lost from the ethyl group at C-8, making this a vinyl residue like that at C-3. The two compounds can thus be named in terms of phytoporphyrin: magnesium 31,32,171,172-tetradehydro-132-(methoxycarbonyl)phytoporphyrinate and magnesium 31,32,81,82,171,172-hexadehydro-132-(methoxycarbonyl)phytoporphyrinate.
Synonym: chlorofucin.
(05 Mar 2000)
chlorophyll d -CH==CH2 replaced by -CO-CH3 in the chlorophyll structure;the chlorophyll found in red algae (Rhodophyceae), together with chlorophyll a.
(05 Mar 2000)
chlorophyll esterase A reversible hydrolyzing enzyme catalyzing the removal of the phytyl group from a chlorophyll, leaving a chlorophyllide.
Synonym: chlorophyll esterase.
(05 Mar 2000)
chlorophyll unit The number of chlorophyll molecules required to reduce one molecule of carbon dioxide by photosynthesis.
(05 Mar 2000)
water-soluble chlorophyll derivatives The copper complex of sodium and/or potassium salts of saponified chlorophyll, used topically for deodorization of chronic lesions and to promote wound repair.
(05 Mar 2000)
acetoacetyl-CoA synthetase <enzyme> Catalyses the conversion of acetoacetate and CoA in the presence of ATP to yield AMP, pyrophosphate and acetoacetyl-CoA; the latter is the first intermediate in cholesterogenesis; also acts more slowly on l-3-hydroxybutanoate
Registry number: EC 6.2.1.16
Synonym: acetoacetyl-CoA ligase, acetoacetate-CoA ligase, acetoacetyl-coenzyme a synthetase
(26 Jun 1999)
acetyl-CoA synthetase A ligase that catalyses the reaction of acetate and CoA and ATP to form AMP, pyrophosphate, and acetyl-CoA. A key step in the activation of acetate.
Synonym: acetate thiokinase, acetate-CoA ligase, acetyl-activating enzyme, acetyl-CoA synthetase.
(05 Mar 2000)
acid cholesterol ester synthetase <enzyme> Aortal enzyme, does not require exogenous ATP or CoA; reverse reaction of cholesterol esterase
Registry number: EC 3.1.1.-
Synonym: cholesterol ester synthetase
(26 Jun 1999)
acyl-CoA synthetase General term for enzymes that form acyl-CoA, now called ligases, specifically, long-chain fatty acid-CoA ligase.
(05 Mar 2000)
acyl protein synthetase <enzyme> Component of the fatty acid reductase complex of luminescent bacteria
Registry number: EC 2.3.1.-
Synonym: luxe gene product, fatty acyl-protein synthetase
(26 Jun 1999)
aerobactin synthetase <enzyme> Condenses 2 molecules of n-epsilon-acetyl-n-epsilon-hydroxylysine with citric acid to form aerobactin
Registry number: EC 4.1.3.-
(26 Jun 1999)
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