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cation <chemistry> A positively-charged ion.
(16 Mar 1998)
cation exchange The process by which a cation in a liquid phase exchanges with another cation present as the counter-ion of a negatively charged solid polymer (cation exchanger). A cation-exchange reaction in removal of the Na+ of a sodium chloride solution is RSO3-H+ + Na+ &rarr; RSO3-Na+ + H+ (R is the polymer, RSO3- is the cation exchanger); if this is combined with the anion-exchange reaction, NaCl is removed from the solution (desalting). Cation exchange may also be used chromatographically, to separate cations, and medicinally, to remove a cation; e.g., H+, from gastric contents, or Na+ and K+ in the intestine.
See: anion exchange.
(05 Mar 2000)
cation exchange resins High molecular weight insoluble polymers which contain functional cationic groups that are capable of undergoing exchange reactions; used in various types of chromatography; also to treat hyperkalaemia.
(12 Dec 1998)
cation exchanger An insoluble solid (usually a polystyrene or a polysaccharide) that has negatively charged radicals attached to it (e.g., -COO-, -SO3-), which can attract and hold cations that pass by in a moving solution if these are more attracted to the acid groups than the counter ion present.
(05 Mar 2000)
cation exhange resin <chemistry> An insoluble resin with fixed anionic groups which is used in chromatography to separate cationic molecules.
(16 Mar 1998)
cation-anion difference <biochemistry> The difference between the sum of the measured cations and anions in the plasma or serum calculated as follows: (Na + K) -(Cl + HCO3) = &lt; 20 mmol/l. Elevated values may occur in diabetic or lactic acidosis; normal or low values occur in bicarbonate-losing metabolic acidoses.
Synonym: cation-anion difference.
(05 Mar 2000)
cation-exchange resin See: cation exchange, cation exchanger.
(05 Mar 2000)
cationic Referring to positively charged ions and their properties.
(05 Mar 2000)
cationic detergents Detergent's, such as the amine salts or quaternary ammonium or pyridinium compounds of long-chain fatty acids, that have positively charged groups attached to the larger hydrophobic portions.
(05 Mar 2000)
cationic protein <biochemistry> Proteins of azurophil granules of neutrophils, rich in arginine. A chymotrypsin like protease found in azurophil granules is also very cationic as is cathepsin G and neutrophil elastase.
Eosinophil cationic protein (21 kD) is particularly important because it damages schistosomula in vitro.
(16 Mar 1998)
cationised ferritin <chemical> Ferritin, treated with dimethyl propanediamine and used to show, in the electron microscope, the distribution of negative charge on the surface of a cell.
The amount of cationic ferritin binding is very approximately related to the surface charge.
(16 Mar 1998)
cationogen A substance that gives rise to positively charged ions.
(05 Mar 2000)
cations Postively charged atoms, radicals or groups of atoms which travel to the cathode or negative pole during electrolysis.
(12 Dec 1998)
cations, divalent Positively charged atoms, radicals or groups of atoms with a valence of plus 2, which travel to the cathode or negative pole during electrolysis.
(12 Dec 1998)
cations, monovalent Positively charged atoms, radicals or group of atoms with a valence of plus 1, which travel to the cathode or negative pole during electrolysis.
(12 Dec 1998)
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