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carbon-carbon double bond isomerases <enzyme> Enzymes that catalyze the shifting of a carbon-carbon double bond from one position to another within the same molecule.
Registry number: EC 5.3.3
(12 Dec 1998)
carbon-carbon ligases <enzyme> Enzymes that catalyze the joining of two molecules by the formation of a carbon-carbon bond. These are the carboxylating enzymes and are mostly biotinyl-proteins.
Registry number: EC 6.4
(12 Dec 1998)
carbon-carbon lyases <enzyme> Enzymes that catalyze the cleavage of a carbon-carbon bond by means other than hydrolysis or oxidation. This subclass contains the decarboxylases, the aldehyde-lyases, and the oxo-acid-lyases.
Registry number: EC 4.1
(12 Dec 1998)
asymmetric Not symmetrical; denoting a lack of symmetry between two or more like parts.
(05 Mar 2000)
asymmetric centre <chemistry> Same as a chiral centre, a tetrahedral carbon atom that bears four different substituents.
(09 Jan 1998)
asymmetric disulfide <chemistry> Disulfide which is not symmetric on both sides of the -s-s- linkage; e.g., the disulfide formed between coenzyme A and glutathione or between cysteine and coenzyme A or glutathione.
Synonym: asymmetric disulfide.
(05 Mar 2000)
asymmetric motor neuropathy Neuropathy in which the loss of function is more marked in the extremities of one side of the body, old term for diabetic polyradiculopathy.
(05 Mar 2000)
active carbon dioxide Activated carbon dioxide, a complex of N-carboxybiotin (biotin + CO2) and an enzyme; the form in which carbon dioxide is added to other molecules in carboxylations; e.g., to methylcrotonyl-CoA to form beta-methylglutaconyl in the catabolism of leucine, and to acetyl-CoA to form malonyl-CoA.
See: acetyl-CoA carboxylase.
(05 Mar 2000)
anomeric carbon The reducing carbon of a sugar; C-1 of an aldose, C-2 of a 2-ketose.
(05 Mar 2000)
arteriovenous carbon dioxide difference <physiology> The difference in carbon dioxide content (in ml per 100 ml blood) between arterial and venous blood.
(05 Mar 2000)
carbon <chemistry, element> Sixth element (Z=6) in the periodic table, has 6 protons, often described as the basis of life on earth because of its chemical properties, has potential for use with silicon as a low-activation structural material for fusion reactors, in the form silicon carbide.
Carbon tiles are often used in plasma-facing components because its low Z makes carbon a relatively nice impurity. It is also useful as a neutron moderator.
See: low-activation materials, plasma-facing components.
Abbreviation: C
(13 Nov 1997)
carbon-11 A cyclotron-produced, positron-emitting radioisotope of carbon with a half-life of 20.3 minutes; used in positron-emitting tomography.
(05 Mar 2000)
carbon-12 The standard of atomic mass, 98.90% of natural carbon.
(05 Mar 2000)
carbon-13 A stable natural isotope, 1.1% of natural carbon.
(05 Mar 2000)
carbon-14 A beta-emitter with a half-life of 5715 years, widely used as a tracer in studying various aspects of metabolism; naturally occurring 14C, arising from cosmic ray bombardment, is used to date relics containing natural carbonaceous materials.
(05 Mar 2000)
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