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Victor-Michaelis-Menten equation <chemistry> Equation derived from a simple kinetic model for a single-substrate non-cooperative enzyme-catalyzed reaction that successfully accounts for the hyperbolic adsorption isotherm) relationship between substrate concentration and reaction rate.
V = Vmax x S/(S + Km), where V is the initial velocity of the reaction, Km is the Michaelis constant, Vmax is the maximum rate approached by very high substrate concentrations and S is the initial substrate concentration.
Similar equations can be derived for conditions in which the product is present and for multisubstrate enzymes.
Synonym: Victor-Michaelis-Menten equation.
(12 Jul 2000)
Michaelis complex Binary complex of an enzyme.
(05 Mar 2000)
Michaelis constant <chemistry> The true dissociation constant for the enzyme-substrate binary complex in a single-substrate rapid equilibrium enzyme-catalyzed reaction (usually symbolised by Ks), the concentration of the substrate at which half the true maximum velocity of an enzyme-catalyzed reaction is achieved (when velocities are measured under initial rate and steady state conditions).
The ratio of rate constants (k2 + k3)/k1 in the single-substrate enzyme-catalyzed reaction: E + S &dblarr; ES &dblarr; E + products where E represents the free enzyme, S is the substrate, and ES is the central binary complex. The expression for the Michaelis constant will be more complex for multisubstrate reactions.
An apparent Michaelis constant is a constant determined either under conditions that are not strictly steady state and initial rate or one that varies with the concentration of one or more cosubstrates.
See: Michaelis-Menten equation.
Synonym: Michaelis-Menten constant.
(05 Mar 2000)
Michaelis-Gutmann body <radiology> A rounded homogenous or concentrically laminated body, 1 to 10 u in diameter, containing calcium apatite and iron; found within macrophages in the bladder wall in malakoplakia.
(12 Jul 2000)
Michaelis, Leonor <person> German-U.S. Chemist, 1875-1949.
See: Michaelis-Gutmann body, Michaelis constant, Michaelis-Menten constant, Michaelis-Menten equation, Michaelis-Menten hypothesis.
(05 Mar 2000)
Michaelis-Menten constant <chemistry> The true dissociation constant for the enzyme-substrate binary complex in a single-substrate rapid equilibrium enzyme-catalyzed reaction (usually symbolised by Ks), the concentration of the substrate at which half the true maximum velocity of an enzyme-catalyzed reaction is achieved (when velocities are measured under initial rate and steady state conditions).
The ratio of rate constants (k2 + k3)/k1 in the single-substrate enzyme-catalyzed reaction: E + S &dblarr; ES &dblarr; E + products where E represents the free enzyme, S is the substrate, and ES is the central binary complex. The expression for the Michaelis constant will be more complex for multisubstrate reactions.
An apparent Michaelis constant is a constant determined either under conditions that are not strictly steady state and initial rate or one that varies with the concentration of one or more cosubstrates.
See: Michaelis-Menten equation.
Synonym: Michaelis-Menten constant.
(05 Mar 2000)
Michaelis-Menten equation <chemistry> Equation derived from a simple kinetic model for a single-substrate non-cooperative enzyme-catalyzed reaction that successfully accounts for the hyperbolic adsorption isotherm) relationship between substrate concentration and reaction rate.
V = Vmax x S/(S + Km), where V is the initial velocity of the reaction, Km is the Michaelis constant, Vmax is the maximum rate approached by very high substrate concentrations and S is the initial substrate concentration.
Similar equations can be derived for conditions in which the product is present and for multisubstrate enzymes.
Synonym: Victor-Michaelis-Menten equation.
(12 Jul 2000)
Michaelis-Menten hypothesis <chemistry> That a complex is formed between an enzyme and its substrate (the O'Sullivan-Tompson hypothesis), which complex then decomposes to yield free enzyme and the reaction products (Brown hypothesis), the latter rate determining the overall rate of substrate-product conversion.
See: Michaelis-Menten constant, Michaelis-Menten equation.
(05 Mar 2000)
acquired platelet function defect <haematology> Platelet function can be affected by a number of different disease processes including polycythaemia vera, leukaemia, myelofibrosis, renal failure, multiple myeloma and some medications (for example penicillins, salicylates, phenothiazines).
Disturbed blood clotting can be manifested by: easy bruising, bleeding gums, nosebleeds, abnormal vaginal bleeding, rectal bleeding, skin rash, vomiting blood, coughing up blood or blood in the urine. A measure of bleeding time and coagulation profile will be part of the evaluation.
(29 Dec 1997)
allomeric function The combined function of the several segments of the spinal cord and medulla, communicating with each other by means of the white matter.
(05 Mar 2000)
aperture function <microscopy> In a diffraction-limited optical system, the function that determines the relationship between the image and each point in the object. Modifying the aperture function changes the image according to the modified Fourier-filtering (or optical filtration) property of the aperture.
(05 Aug 1998)
arousal function The ability of a sensory event to arouse the cortex to vigilance or readiness.
(05 Mar 2000)
atrial function The haemodynamic and electrophysiological action of the atria.
(12 Dec 1998)
atrial function, left The haemodynamic and electrophysiological action of the left atrium.
(12 Dec 1998)
atrial function, right The haemodynamic and electrophysiological action of the right atrium.
(12 Dec 1998)
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